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The Telekom Affair – In May 2007, several former riders admitted to using banned substances (including EPO ) while riding for the team in the mid-1990s, including Erik Zabel , Rolf Aldag , Brian Holm , [143] Bjarne Riis , [151] Bert Dietz , Udo Bölts and Christian Henn including the seasons in which Riis and Jan Ullrich won the Tour de France. [141] Team doctors Andreas Schmid and Lothar Heinrich also confessed to participating and administering banned substances. The latter was Team Telekom's sporting director until 3 May 2007, when he was suspended following allegations published in former team member Jef d'Hont 's book. [152]

Valproic acid was first synthesized in 1882 by Beverly S. Burton as an analogue of valeric acid , found naturally in valerian . [66] Valproic acid is a carboxylic acid , a clear liquid at room temperature. For many decades, its only use was in laboratories as a "metabolically inert" solvent for organic compounds. In 1962, the French researcher Pierre Eymard serendipitously discovered the anticonvulsant properties of valproic acid while using it as a vehicle for a number of other compounds that were being screened for antiseizure activity. He found it prevented pentylenetetrazol -induced convulsions in laboratory rats . [67] It was approved as an antiepileptic drug in 1967 in France and has become the most widely prescribed antiepileptic drug worldwide. [68] Valproic acid has also been used for migraine prophylaxis and bipolar disorder. [69]

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